Warehouse Types

Dangerous Goods Warehouse / Hazardous Materials Warehouse

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Description of dangerous goods warehouse

Dangerous goods warehouse (also known as hazardous materials warehouse or hazmat warehouses) represents a storage area that allows to store "dangerous goods" (e.g. mixtures, solutions, substances) that are so classified according to the legal regulation. A "dangerous good" is classified in different dangerous goods classes or storage classes. The improper or even illegal storage of "dangerous goods" can have serious consequences for a company.

Roughly speaking, the regulations on the storage of hazardous substances are regulated in the resolution Technical Rule on Hazardous Substances (TRGS 510 Storage of Hazardous Substances) and in the Ordinance on Hazardous Substances. TRGS 510 applies to hazardous substances in mobile containers, including during storage and retrieval, in the course of transports within the warehouse, and also when spilled hazardous substances have to be removed. All other activities, such as transferring and filling, are expressly excluded from the scope.

What are dangerous / hazardous materials?

Substances and preparations can be depending on their chemical, physical, physiological, toxicological and radiological properties:

explosivetoxic
toxic to reproductionoxidising
harmful to healthmutagenic
extremely flammablecorrosive
dangerous for the environmenthighly flammable
irritantinfectious
flammablesensitising
radioactivevery toxic
carcinogenichazardous to water

 

All of these hazards can play a role in storage and require separate measures. When determining which measures must be taken for the respective group of substances, the quantity to be stored is the decisive factor.

Hazardous goods are materials that have one of the above hazardous properties and thus pose a danger to public safety or order or to important common property, as well as endangering the life and health of persons, animals and others.

A further distinction is made between hazardous goods and hazardous materials.

  • Hazardous goods: According to the dangerous goods regulations, this includes substances and objects that pose a danger in the event of accidents or improper action.
  • Hazardous materials: Here, the hazardous substances law regulates that persons working with the respective substances do not come to harm.

Most hazardous materials are also considered hazardous goods during transport.

Requirements for a dangerous goods warehouse / hazardous materials warehouse

Differentiation from a technical and organisational point of view:

  • from a technical point of view, e.g.
    • Sufficient attack routes for the fire brigade
    • Size of fire compartments
    • Fire-retardant / -resistant walls and ceilings, doors and gates
    • Fire detection
    • Fire fighting e.g. fire extinguishers, stationary or semi-mobile (semi-stationary) extinguishing systems with extinguishing agents adapted to the stored goods
    • Fire water supply, if necessary, storage of water
    • Fire water retention
    • Floor sealing
    • Resistant collection areas for leaking liquids
    • Explosion protection equipment
    • Gas warning system
    • Ventilation system
    • Smoke and heat extraction system
  • from an organisational point of view, e.g.
    • Regulation of access by unauthorised persons
    • Prohibition of common storage
    • Marking of storage rooms
    • Storage list (hazardous substances register)
    • Operating instructions
    • Training and instruction
    • Proof of maintenance and servicing
    • Compliance with the deadlines for periodic inspections (expert inspection)
    • Safeguarding against risks by taking out insurance, such as fire insurance, business interruption insurance, water damage liability insurance, environmental damage liability insurance

Storage of dangerous goods

The construction of a dangerous goods storage facility thus requires high financial investments and the operation requires far-reaching organisational measures. The economic risk is additionally increased by possible claims for damages under civil law, fines or even criminal consequences that may result from mistakes or violations of legal requirements.

Three cases can be distinguished when storing dangerous materials:

  1. The dangerous materials may be stored together
  2. The dangerous materials must be stored separately
  3. The dangerous materials must be stored in separate dangerous goods storage facilities.

First case: It does not pose an additional problem.

Second case: Hazardous substances must be stored separately if an increased hazard results from storing them together.

Examples:

  • different extinguishing agents required for fire-fighting operations
  • different temperatures at which the hazardous substances are stored
  • hazardous substances that form flammable or toxic gases together
  • or fires that may occur as a result of the combination

Separation is said to occur when the spatial distance between the storage spaces is large enough or the storage spaces are separated by barriers (e.g. walls, non-flammable liquids and solids). Also in the case of storage in different rooms.

Third case: Storage in different or separate dangerous goods storage areas.

The following table describes the three cases:

Hazmat warehouse, hazardous materials warehouse, hazardous substances warehouse
Table of dangerous goods storage as per storage classes

Dangerous goods classes

Class 1- Explosive substances

Explosives and articles containing explosives

Class 2 - Gases

Class 2.1 Gases (flammable)
Class 2.2 Gases (non-flammable)
Class 2.3 Gases (toxic)

Gases are substances which have a vapour pressure of more than 3 bar at 50 °C or are completely gaseous at 20 °C and 1013 mbar pressure. This class includes compressed (condensed), liquefied or dissolved gases.

Examples: Propane gas, hydrogen, hairspray, acetylene.

Class 3 - Flammable liquids

Class 3 includes substances and articles which are liquid at 20 °C and 1013 mbar, have a maximum vapour pressure of 3 bar at 50 °C, are not completely gaseous at 20 °C and 1013 mbar, and have a flash point not exceeding 61 °C. Flammable liquids and molten solids having a flashpoint above 61 °C and heated to or above their flashpoint are also substances of Class 3.

Examples: Petrol, alcohol, certain liquefied metals.

Class 4.1 - Flammable solids

Substances of Class 4.1 are highly flammable solids and articles which may be ignited by flying sparks or which may cause fire by friction. Furthermore, Class 4.1 includes self-reactive substances which tend to undergo highly exothermic decomposition at abnormally high temperatures or by contact with impurities. Explosive substances which are moistened with such a quantity of water or alcohol or which contain such a quantity of plasticising or inerting agent that the explosive properties are suppressed are also substances of Class 4.1.

Examples: Rubber residues, matches, sulphur.

Class 4.2 - Substances liable to spontaneous combustion

Substances liable to spontaneous combustion are substances including mixtures and solutions (liquid or solid) which, in contact with air, ignite even in small quantities within 5 minutes. Also substances and articles, including mixtures and solutions, which are capable of self-heating in contact with air. These substances can only ignite in larger quantities (several kg) and after longer periods of time (hours or days).

Examples: White phosphorus, coal (of vegetable origin), fish meal, varnishes.

Class 4.3 - Substances which form flammable gases with water

Substances of Class 4.3 and articles containing substances of this Class which, on reaction with water, emit flammable gases which may form explosive mixtures with air.

Examples: Sodium, carbide, zinc dust, trichlorosilane.

Class 5.1 - Flammable (oxidising) substances

Substances which need not necessarily be flammable themselves and which may (generally by releasing oxygen) cause a fire or promote the fire of other substances are substances of Class 5.1.

Examples: Hydrogen peroxide, potassium chlorate, sodium chlorate ("weed ex"), fertilisers containing ammonium nitrate.

Class 5.2 - Organic peroxides

Class 5.2 includes all organic peroxides containing more than 1 % active oxygen and more than 1 % hydrogen peroxide or more than 0.5 % active oxygen and more than 7 % hydrogen peroxide.

Examples: Dibenzoyl peroxide (hardener paste for polyester resin), methyl ethyl ketone peroxide (hardener for two-component lacquers).

Class 6.1 - Toxic substances

Class 6.1 includes substances which are known from experience or may be assumed from experimental studies on animals to be capable of causing damage to the health or death of a human being after inhalation, ingestion or contact with the skin in a single or short exposure in relatively small quantities.

Examples: Hydrogen cyanide (prussic acid), arsenic, pesticides.

Class 6.2 - Infectious substances

All substances known or suspected to contain pathogens known or suspected to cause infectious diseases in animals or humans are substances of Class 6.2. Infectious substances are substances known or suspected to contain pathogens. Pathogens are micro-organisms (including bacteria, viruses, rickettsiae, parasites and fungi) or recombinant micro-organisms (hybrids or mutants) known or suspected to cause infectious diseases in animals or humans.

Class 7 - Radioactive material

All radioactive substances and articles containing radioactive substances are substances of Class 7.

Examples: Uranium, plutonium, certain medical instruments, technical testing equipment for product control.

Class 8 - Corrosive substances

Class 8 includes all substances which, by chemical action, corrode the skin or mucous membranes with which they come into contact. Furthermore, Class 8 also includes substances which, if released, may cause damage to or destroy other goods or means of transport, and substances which first form corrosive liquids with water or corrosive vapours or mists with atmospheric moisture.

Examples: Sulphuric acid, caustic soda.

Class 9 - Miscellaneous dangerous substances and articles

Class 9 includes all substances and articles presenting a danger during carriage which do not fall under any of the above classes.

Examples: Asbestos, lithium batteries, airbags.

Small quantity regulations for dangerous goods

A small quantity is defined as the storage of a total of no more than 50 kg net. Separate warehouses are not required for dangerous goods in this quantity band; they may also be stored in other rooms, including workrooms.

However, some additional requirements are imposed on certain dangerous goods:

  • Flammable liquids must be stored in a steel cabinet if they exceed 5 litres.
  • For more than 20 litres, storage should be in a cabinet with a fire resistance rating of more than 15 minutes. In addition, the containers must be placed in drip pans and must be earthed in the event of the possible occurrence of an explosive atmosphere.
  • A maximum of 50 applies to compressed gas cartridges and aerosol dispensers.
  • Toxic, very toxic and carcinogenic substances must always be kept under lock and key.
  • Oxidising substances must not be stored in the immediate vicinity of acutely toxic and flammable substances.

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